Enhancing Polysulfone Mixed-Matrix Membranes with Amine-Functionalized Graphene Oxide for Air Dehumidification and Water Treatment
نویسندگان
چکیده
Porous low-pressure membranes have been used as active in water treatment and support for thin-film composite desalination gas separation applications. In this article, microfiltration polysulfone (PSf)mixed-matrix (MMM) containing amine-functionalized graphene oxide (GO-NH2) were fabricated via a phase inversion process characterized using XPS, SEM, AFM, DMA, XRD, contact angle measurements. The effect of GO-NH2 concentration on membrane morphology, hydrophilicity, mechanical properties, oil–water performance was analyzed. Significant enhancements porosity, permeability, selectivity achieved at very low concentrations (0.05–0.2 wt.%). particular, the permeability 0.2 wt.% 92% higher than pure PSf membrane, oil rejection reached 95.6% compared to 91.7% membrane. stiffness also increased by 98% Importantly, antifouling characteristics PSf-GO-NH2 MMMs significantly improved. When filtering 100 ppm bovine serum albumin (BSA) solution, demonstrated slower flux decline an impressive recovery after washing. Notably, control showed only 69%, while with exceptional 88%. Furthermore, exhibited enhanced humidity removal performance, permeance increase from 13,710 16,408. These results indicate that MMM is excellent candidate reliable applications, notable improvements performance.
منابع مشابه
Hydrophobicity Properties of Graphite and Reduced Graphene Oxide of The Polysulfone (PSf) Mixed Matrix Membrane
Hydrophobicity properties of graphite and green synthesized graphene (gsG) from exfoliated graphite/GO towards polymer membrane characteristic and properties at different weight percentage concentrations (1, 2, 3, 4 and 5 wt. %) were investigated. PSf/graphite and PSf/gsG membranes were characterized in term of hydrophobicity, surface bonding, surface roughness and porosity. FTIR peaks revealed...
متن کاملMethod for increasing permeability for O2/N2 separation with mixed- matrix membranes of water-stable MIL-101 and polysulfone
1.1 Materials Chromium nitrate nonahydrate (Cr(NO3)2·9H2O, 99%) and hydrofluoric acid (analysis grade) were obtained from Acros Organics. Benzene-1,4-dicarboxylic acid (H2BDC, 99%) was acquired from Aldrich. Dichloromethane (DCM, >99.9%), N,N-dimethylformamide (DMF, 99.9%) and Ethanol (99.9%) were purchased from Prolabo. Polysulfone (PSF) Ultason S 6010 Natural was provided by BASF AG, Ludwigsh...
متن کاملPolysulfone Ultrafiltration Membranes Modified with Carbon-Coated Alumina Supported NiTiO2 Nanoparticles for Water Treatment: Synthesis, Characterization and Application
This paper reports on the synthesis and characterisation of polysulfone (PSf) ultrafltration (UF) membranes modifed with carbon coated alumina Ni-doped titanium dioxide (CCA/Ni-TiO2) nanoparticles. The syntheses of the membranes was carried out using the phase inversion process. The ...
متن کاملPurified and Functionalized MWCNTs: Application In CO2/CH4 Separation Using Mixed Matrix Membranes
To fabricate a defect free and high performance mixed matrix membrane (MMM), one approach is the functionalization of inorganic nanofillers (as dispersed phase) in the organic polymer matrix (as continuous phase) to modify the interactions between two phases. For this purpose,, raw multi-walled carbon nanotubes (rMWCNTs) were purified by acid mixture (HNO3/H2SO<sub...
متن کاملUnderstanding water permeation in graphene oxide membranes.
Water transport through graphene-derived membranes has gained much interest recently due to its promising potential in filtration and separation applications. In this work, we explore water permeation in graphene oxide membranes using atomistic simulations and theoretical analysis, by considering flow through the interlayer gallery, expanded channels such as wrinkles of interedge spaces, and po...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Membranes
سال: 2023
ISSN: ['2077-0375']
DOI: https://doi.org/10.3390/membranes13070678